催化作用
对映选择合成
化学
材料科学
化学工程
组合化学
有机化学
工程类
作者
Heng Zhang,Shucheng Liu,Qiuxin Zhang,Kun Hong,Jiuling Li,Xingchen Yan,Jianming Pan
标识
DOI:10.1002/slct.202405224
摘要
Abstract Chiral substances play a pivotal role in numerous contemporary fields, and their synthesis heavily relies on chiral catalysts. However, traditional homogeneous catalysts suffer from significant drawbacks, including difficulty in separation from products and nonrecyclability. Immobilization of homogeneous catalysts onto a specific carrier offers an excellent solution to these challenges, significantly reducing the production cost. Consequently, this approach has emerged as an inevitable trend in the development of chiral catalysts. This review comprehensively summarizes representative examples of an asymmetric catalytic reactions using chiral catalysts immobilized on inorganic carriers over the last decade, classifies them according to the type of carrier, and elucidates the loading techniques and recycling methods associated with these carriers.
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