流变学
压缩性
Zeta电位
材料科学
单层
粒子(生态学)
化学物理
热力学
机械
纳米技术
纳米颗粒
复合材料
物理
海洋学
地质学
作者
Maximilian M. Schmidt,José Ruiz-Franco,Steffen Bochenek,Fabrizio Camerin,Emanuela Zaccarelli,Andrea Scotti
标识
DOI:10.1103/physrevlett.131.258202
摘要
In situ interfacial rheology and numerical simulations are used to investigate microgel monolayers in a wide range of packing fractions, ${\ensuremath{\zeta}}_{2D}$. The heterogeneous particle compressibility determines two flow regimes characterized by distinct master curves. To mimic the microgel architecture and reproduce experiments, an interaction potential combining a soft shoulder with the Hertzian model is introduced. In contrast to bulk conditions, the elastic moduli vary nonmonotonically with ${\ensuremath{\zeta}}_{2D}$ at the interface, confirming long-sought predictions of reentrant behavior for Hertzian-like systems.
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