光催化
氮化碳
材料科学
异质结
聚合
碳纤维
化学工程
氮化物
量子效率
氢
催化作用
光化学
纳米技术
光电子学
化学
复合数
聚合物
复合材料
有机化学
图层(电子)
工程类
作者
Senpei Tang,Shitao Yang,Yuanyuan Chen,Yi Yang,Zhenhui Li,Lu Zi,Ying Liu,Yingchun Wang,Zhiping Li,Zaihui Fu,Youji Li
出处
期刊:Carbon
[Elsevier]
日期:2023-01-01
卷期号:201: 815-828
被引量:15
标识
DOI:10.1016/j.carbon.2022.09.071
摘要
Graphitic phase carbon nitride (CN) is a safe and green photocatalyst, but the activity of the pristine CN photocatalyst is still unsatisfactory due to the significant recombination of photogenerated charges, so it is still challenging to realize the practical application of CN for photocatalysis. Herein, we report that a mechanical mixture consisting of pre-thermally polymerized melamine (Me) and 3-amino-1,2,4-triazole (AT) can be transformed into a crystalline isotype heterojunction material (ISCNMT) by ionothermal synthesis. A series of characterizations and photocatalytic tests demonstrate that the polymerizability, porosity and photoelectric conversion efficiency of the constructed ISCNMT have been improved. The photogenerated charge pairs of the ISCNMT can migrate in S-scheme, indicating that ISCNMT retains the strongest reduction capacity and greatly improving the separation efficiency of photogenerated charge pairs. As a result, the ISCNMT exhibits outstanding performance. Its catalytic efficiency for visible light-triggered hydrogen evolution from water can reach 9.64 mmol·g−1·h−1 with an apparent quantum efficiency (AQE) of 26.23%, which is 21 or 45 times higher than that of the carbon nitride material directly polymerized by Me or AT (CNM or CNT). In addition, the ISCNMT has a catalytic efficiency of 15.64 μmol·g−1·h−1 for photocatalysis CO2 reduction under water vapor. This work provides a facile pathway for designing S-scheme isotype heterojunction CN-based photocatalysts for the efficient conversion of solar energy.
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