电解质
材料科学
自愈
电池(电)
聚丙烯酸钠
水溶液
化学工程
自愈水凝胶
纳米技术
化学
高分子化学
电极
有机化学
工程类
病理
物理化学
功率(物理)
物理
替代医学
原材料
医学
量子力学
作者
Yan Huang,Jie Liu,Jiaqi Wang,Mengmeng Hu,Funian Mo,Guojin Liang,Zhi Chen
标识
DOI:10.1002/anie.201805618
摘要
Self-healing solid-state aqueous rechargeable NiCo||Zn batteries are inherently safe and have a high energy density and mechanical robustness. However, the self-healability of solid-state batteries has only been realized by a few studies in which electron/ion-inactive self-healable substrates are utilized. This arises from the lack of self-healable electrolytes. Now an intrinsically self-healing battery has been designed that utilizes a new electrolyte that is intrinsically self-healable. Sodium polyacrylate hydrogel chains are crosslinked by ferric ions to promote dynamic reconstruction of an integral network. These non-covalent crosslinkers can form ionic bonds to reconnect damaged surfaces when the hydrogel is cut off, providing an ultimate solution to the intrinsic self-healability problem of batteries. As a result, this NiCo||Zn battery with this hydrogel electrolyte can be autonomically self-healed with over 87 % of capacity retained after 4 cycles of breaking/healing.
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