膨胀的
材料科学
烧焦
坡缕石
锥形量热计
聚磷酸铵
差示扫描量热法
阻燃剂
热重分析
极限氧指数
热重分析
复合材料
扫描电子显微镜
热稳定性
热分解
化学工程
矿物学
热解
化学
有机化学
粘土矿物
工程类
物理
热力学
作者
Jingfang Zhang,Zilong Liang,Jingxuan Liu,Yange Wan,Xin Tao,Haijun Zhang,Mingchao Wang
标识
DOI:10.1016/j.porgcoat.2022.106801
摘要
Aiming to improve the fire resistance, the synergistic effects of palygorskite and expandable graphite (EG) on water-based intumescent fire retardant (IFR) coatings were investigated in details by fire resistance test, limiting oxygen index (LOI) test, vertical burning (UL-94) tests, thermogravimetry (TGA)-differential scanning calorimeter (DSC) test, and cone calorimeter test. The char residues were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Brunauer-Emmett-Teller test (BET). The backside temperature of the substrate of sample 3-3 with 3 wt% of EG and 3 wt% of palygorskite addition (SP3-3) was recorded to be 150 °C after 120 min fire test, 46.5% lower than that of the sample 1 with no addition (SP1). The SP3-3 had the best fire retardant performance reflected by UL-94 V0 flammability rating and the LOI value as high as 35.8%. The TG-DSC analysis showed palygorskite can increase the thermal stability and decrease the decomposition rate of the coatings. The cone calorimeter test demonstrated SP3-3 remarkably reduce the value of peak heat release rate and peak smoke production release by 64.1% and 85.7%, respectively. The XRD analysis confirmed that the decomposition compounds of ammonium polyphosphate, fillers, and palygorskite can react and form a ceramic-like protective barrier, which enhanced the thermal stability and char yield. In addition, the SP3-3 had shown best results in char expansion and char morphology.
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