超级电容器
材料科学
活性炭
壳体(结构)
氢氧化物
芯(光纤)
电化学
化学工程
纤维
电极
微波食品加热
复合材料
无机化学
化学
有机化学
吸附
电信
工程类
物理化学
计算机科学
作者
Liuxuan Luo,Shirui Wang,Yecheng Zhou,Wen Yan,Haili Gao,Lingcong Luo,Jianping Deng,Guanben Du,Mizi Fan,Wenxia Zhao
标识
DOI:10.1016/j.electacta.2022.140148
摘要
• NiCo-LDH nanorod arrays microsphere are spontaneously fabricated on melt-spinning ACFs. • The synergistic effect contributes to improved electrochemical performance. • A capacitance of 1453.3 F g −1 at 1 A g −1 were obtained by NiCo-LDH@ACF-120 electrodes. • The supercapacitor device shows high energy density of 52.2 Wh kg −1 at 800 W kg −1 . • The capacitance retention of supercapacitor device is 79.8 % after 10 000 cycles. Activated carbon fibers (ACFs) are prepared from the discarded fir wood using two-step melt-spinning and CO 2 activation post-treatment. Then, composites composed of these ACFs and Ni, Co-layered double hydroxides (NiCo-LDH@ACF) are synthesized by a microwave-assistant hydrothermal strategy. NiCo-LDHs agglomerated around ACFs, forming core-shell structures with sheet- or microsphere-like morphologies, which provide large surface area, hierarchical porosity, and numerous active sites for efficient charge and mass transfer. The NiCo-LDH@ACFs are used as an active material to construct the supercapacitors, the highest of capacitance and the corresponding rate performance of which are equal to 1453.3 F/g at 1 A/g and 78% at 10 A/g by microwave-assistant hydrothermal at 120 °C, respectively. We also use this material to assemble an asymmetric supercapacitor using activated carbon derived from fir bark as a negative electrode. The resulting device demonstrates excellent capacitance (equal to 146.9 F/g at 1.6 V), very high energy density (equal to 52.2 Wh/kg at 800 W/kg), and cycle life (judging by the 79.8% capacitance retention after 10000 cycles).
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