覆盖层
扫描隧道显微镜
结晶学
外延
曲面重建
基质(水族馆)
材料科学
低能电子衍射
电子衍射
单层
低能电子显微镜
凝聚态物理
物理
衍射
纳米技术
图层(电子)
曲面(拓扑)
化学
光学
几何学
电子显微镜
地质学
海洋学
数学
作者
Shamil K. Shaikhutdinov,Michael Ritter,Werner Weiß
出处
期刊:Physical review
日期:2000-09-15
卷期号:62 (11): 7535-7541
被引量:63
标识
DOI:10.1103/physrevb.62.7535
摘要
Formation of an epitaxial iron oxide monolayer on a Pt(100)-hex substrate was studied by scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED). High-resolution STM images reveal a sinusoidal height modulation of the top atomic rows along the [011] direction of the original Pt(100)-hex substrate. This modulation is assigned to the buckling of the top oxygen layer due to the interaction with Pt substrate atoms. Two superstructures, described as $\mathrm{FeO}(111)/\mathrm{P}\mathrm{t}(100)\ensuremath{-}c(2\ifmmode\times\else\texttimes\fi{}10)$ and $(2\ifmmode\times\else\texttimes\fi{}9)$ coincidence structures, coexist on the surface. The latter structure results in a much lower Pendry R factor in dynamical LEED analysis than earlier reported for a $c(2\ifmmode\times\else\texttimes\fi{}10)$ structure. Numerous islands with the same surface structure as the terraces develop on the dense FeO overlayer. They are assigned as the $\mathrm{Pt}(100)\ensuremath{-}(1\ifmmode\times\else\texttimes\fi{}1)$ islands formed during the $\mathrm{hex}\ensuremath{\rightarrow}(1\ifmmode\times\else\texttimes\fi{}1)$ reconstruction of the Pt substrate underneath the FeO(111) bilayer. The islands are rectangular and elongated in the direction of hex reconstruction on the original Pt(100). Combined STM and LEED data clearly indicate that anisotropy in the substrate reconstruction leads to anisotropy of the oxide overlayer.
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