Time Dependent Degradation of Cell in Dye-Sensitized Solar Cell

We report on the time dependent degradation of cell in dye-sensitized solar cells (DSSC). The photovoltaic performance of DSSC over a period of time was investigated in liquid electrolyte based on triiodide/iodide during six days. It was found that the short circuit current density ($j_{sc}$) of the cell dropped from 9.9 to $7mA/cm^2$ while efficiency (${\eta}$) of the cell decreased from 4.4 to 3.3%. The parameters corresponding to fundamental electronic and ionic processes in a working DSSC are determined from the electrochemical impedance spectrascopy (EIS) at open-circuit potential ($V_{oc}$). EIS study of the DSSC in the this work showed that the electron life time ${\tau}_r$ and chemical capacitance $C_{\mu}$ decreased significantly after six days. It was correlated the $j_{sc}$ and efficiency decreased after six days.