氢解
甘油
丙二醇
沮丧的刘易斯对
封面(代数)
催化作用
选择性
路易斯酸
化学
有机化学
机械工程
工程类
作者
Xiaochen Zhao,Jia Wang,Man Yang,Nian Lei,Lin Li,Baolin Hou,Shu Miao,Xiaoli Pan,Aiqin Wang,Tao Zhang
出处
期刊:Chemsuschem
[Wiley]
日期:2017-03-02
卷期号:10 (5): 816-816
标识
DOI:10.1002/cssc.201700326
摘要
The Cover picture shows the selective hydrogenolysis of glycerol to 1,3-propanediol that was catalyzed by in situ-generated analogue of “Frustrated Lewis Pairs” (FLP) with the assistance of H2. The introduction of highly dispersed Au species to Pt/WOx catalysts can enhance the formation of this FLP structure, and results in simultaneously improved 1,3-propanediol selectivity (51.6%) and glycerol conversion (81.1%) under mild reaction conditions (1 MPa H2, 413 K). More details can be found in the Communication by Zhao et al. on page 819 in Issue 5, 2017 (DOI: 10.1002/cssc.201601503).
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