The extraction technology was used to recover copper from wastewater of gold smelting process and the effect of extractant concentration,ratio of oil phase to aqueous phase(O/A),mixing time and pH value was studied.The optimal process condition was obtained as follows: extractant concentration is 20%,O/A is 2:1,mixing time is 3min and pH value is 1.5~2.In the optimal condition,the industrial tests were carried out.The results shows that the extraction rate of copper can be above 95% and copper ionic concentration can be above 36 g/L in stripping solution which meets requirements of copper electrowinning.This process realizes copper recovery in high efficiency.