材料科学
光催化
纳米技术
半导体
工程物理
能量(信号处理)
光电子学
量子力学
工程类
物理
生物化学
催化作用
化学
作者
Danjun Wang,Dan Jun Wang,Jie Zhang,Guo Li,Huidong Shen,Hui Shen,Feng Fu,Gi Xue,Gang Xue,Yi Fang,Fang Yi-Fan
出处
期刊:Journal of Inorganic Materials
[Shanghai Institute of Ceramics]
日期:2015-01-01
卷期号:30 (7): 683-683
被引量:7
摘要
Design and controllable synthesis of catalyst and its property tuning are an interesting subject for physical chemistry, materials chemistry and catalytic chemistry. As a new environmental-purifying technology, semiconductor photocatalytic oxidation technology has arosen worldwide attention. However, conventional photocatalyst exhibits poor utilization of solar energy and low efficient of photogenerated charge separation, which restricts the practical application of the technology. Therefore, it is still a challenging topic to design and synthesize visible-light-response photocatalytic materials with higher utilization efficiency of solar energy. Besides tuning synthesis method(by controlling particle size, morphology, crystallinity and other microstructures, etc), modification is a crucial strategy for the activity enhancement of photocatalyst. In this paper, we reviewed the basic mechanism for the photocatalyst modification from the view of semiconductor energy structure. Taking consideration of the basic mechanism and process of photocatalysis, there are two key modification strategies: chemical structure modification(energy band modification) to broaden the light absorption and surface modifi-cation(surface sensitization, semiconductor combinations and noble metal deposition) to increase life-time of carrier. Suitable band structure is responsible for the visible-light harvesting and effective separation of carrier of semiconductor photocatalyst.
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