Hydrophobe modified expangded perlite were prepared by soaking method.The change law of water absorption,compressive strength and dry density of perlite thermal insulation mortar were investigated by the change of mass-volume concentration and the addition of waterproof agent,basing on the modification of expanded perlite.The results show that the water absorption of perlite can be decreased from 290% to 90%when the surface of expanded perlite is modified by silicone water-proofing agent.With the decreasing of mass-volume concentration,the water absorption of perlite insulation mortar increases,the compressive strength and dry density decrease.The water absorption of perlite insulation mortar can be decreased further by adding water-proofing agent for perlite,supposing the optimal mass-volume concentration is selected.