超空间
游标尺
群(周期表)
对称(几何)
晶体结构
衍射
空间组
结晶学
对称群
物理
纯数学
材料科学
理论物理学
数学物理
数学
X射线晶体学
化学
量子力学
光学
几何学
超对称性
作者
Zhao Zhi-Bo,Ma Ru-Zhang
出处
期刊:Chinese Physics
[Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences]
日期:1988-01-01
卷期号:37 (12): 1940-1940
被引量:2
摘要
The nonstoichiometric compound Ba1+xFe2S4(0.062≤x≤0.143) and the rare earth-transition rnetal tetraborides R1+εFe4B4(ε≈ 0.1, R = Ce, Pr, Nd, Sm, Gd, Tb), both composed of two interpenetrating substructures, are examples of the vernier structures. In present paper, the symmetry of the crystal structure in these two systems is characterized by the superspace group approach developed by de Wolff et al. The superspace group for Ba1+xFe2S4 compound is P1IssI4/mmm and the one for all R1+εFe4B4 compounds is P1Iss(P42/ncm). The diffraction selection rules in the commensurate models for the vernier structures, those often occur and are not related to the systematic absences of the three-dimensional space groups, are explained according to the results of the systematic absences discussed in the superspace. Such diffraction selection rules are very useful to predict where the measurable intensities can be found in the case of crystal structure analysis for the vernier structures.
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