材料科学
阴极
离子
锂(药物)
电化学
电解质
化学工程
锂离子电池
电池(电)
分析化学(期刊)
兴奋剂
作者
Lina Cong,Qin Zhao,Zhao Wang,Yuhang Zhang,Xing-Long Wu,Jingping Zhang,Rongshun Wang,Haiming Xie,Liqun Sun
标识
DOI:10.1016/j.electacta.2016.03.088
摘要
Abstract Layered compounds LiNi 1/3 Co 1/3 Mn 1/3 O 2 have recently received much attention as they have been regarded as a promising cathode materials for industrial application. However, its fast energy density decay and poor rate performance which originate from structure disruption especially at high rate and high cut-off voltage limit its large-scale application. Here, a novel designed concept and facile method were firstly used to fabricate (PO 4 ) 3− polyanions doped layered LiNi 1/3 Co 1/3 Mn 1/3 O 2 (LNMC-(PO 4 ) 0.015 -O 1.94 ) structure, which could offer more stable high-voltage cycling performance and high rate capability. We attribute this improved performance to the robust P tet -O covalence, which will stabilize the oxygen close-packed structure during repeated cycling. Moreover, our stepwise pre-cycling treatments could effectively restrain the formation of micro-cracks and non-crystallization defects, and significantly improve cyclic durability with high charge voltage of 4.7V. The LNMC-(PO 4 ) 0.015 -O 1.94 electrode can still delivers capacity retention of 81% after 200 cycles at a current density of 300mA g −1 . The preliminary results reported here manifest that this novel-designed LNMC-(PO 4 ) 0.015 -O 1.94 material represents an attractive alternative to ultrafast-rate, long-life and high-voltage electrode material for lithium ion batteries.
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