苯甲醛
苯甲醇
电子顺磁共振
光催化
催化作用
营业额
多金属氧酸盐
光化学
产量(工程)
化学
酒
辐照
材料科学
有机化学
核磁共振
物理
冶金
核物理学
作者
Tang Wei,Yanan Liu,Yuzhen Jin,Weixiang Shen,Jian Sun,Pengtao Ma,Jingyang Niu,Jingping Wang
标识
DOI:10.1002/chem.202302921
摘要
An unclassical structure of {Ru(C6H6)}‐based polyoxometalate, Cs6H4[Te2Mo12O46{Ru(C6H6)}]·16.5H2O (1), has been successfully constructed from {Te2Mo12O46}‐type heteropolymolybdate and {Ru(C6H6)} group, which structure type was discovered for the first time. Compound 1 not only possesses strong light‐harvesting ability, but also exhibits high carrier separation efficiency and lower charge transfer resistance. Under visible light irradiation, compound 1 displayed excellent catalytic activity and circularity in the conversion of benzyl alcohol to benzaldehyde (yield = 94%; turnover number = 500; turnover frequency = 20.8 h‐1). Finally, the electron paramagnetic resonance measurement and energy level matching analysis provide theoretical basis for the derivation of the reaction mechanism.
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