Two-dimensional mesoporous metals: a new era for designing functional electrocatalysts

Two-dimensional (2D) mesoporous metals contribute a unique class of electrocatalyst materials for electrochemical applications. The penetrated mesopores of 2D mesoporous metals expose abundant accessible undercoordinated metal sites, while their 2D nanostructures accelerate the transport of electrons and reactants. Therefore, 2D mesoporous metals have exhibited add-in structural functions with great potential in electrocatalysis that not only enhance electrocatalytic activity and stability but also optimize electrocatalytic selectivity. In this Perspective, we summarize recent progress in the design, synthesis, and electrocatalytic performance of 2D mesoporous metals. Four main strategies for synthesizing 2D mesoporous metals, named the CO (and CO container) induced route, halide ion-oriented route, interfacial growth route, and metal oxide atomic reconstruction route, are presented in detail. Moreover, electrocatalytic applications in several important reactions are summarized to highlight the add-in structural functions of 2D mesoporous metals in enhancing electrochemical activity, stability, and selectivity. Finally, current challenges and future directions are discussed in this area. This Perspective offers some important insights into both fundamental investigations and practical applications of novel high-performance functional electrocatalysts.