Charge Dynamics Engineering Sparks Hetero‐Interfacial Polarization for an Ultra‐Efficient Microwave Absorber with Mechanical Robustness

Abstract Microwave absorbers with high efficiency and mechanical robustness are urgently desired to cope with more complex and harsh application scenarios. However, manipulating the trade‐off between microwave absorption performance and mechanical properties is seldom realized in microwave absorbers. Here, a chemistry‐tailored charge dynamic engineering strategy is proposed for sparking hetero‐interfacial polarization and thus coordinating microwave attenuation ability with the interfacial bonding, endowing polymer‐based composites with microwave absorption efficiency and mechanical toughness. The absorber designed by this new conceptual approach exhibits remarkable Ku‐band microwave absorption efficiency (−55.3 dB at a thickness of 1.5 mm) and satisfactory effective absorption bandwidth (5.0 GHz) as well as desirable interfacial shear strength (97.5 MPa). The calculated differential charge density depicts the uneven distribution of space charge and the intense hetero‐interfacial polarization, clarifying the structure–performance relationship from a theoretical perspective. This work breaks through traditional single performance‐oriented design methods and ushers a new direction for next‐generation microwave absorbers.