para-Fluoro/thiol click chemistry-driven pentafluorostyrene-based block copolymer self-assembly: to mimic or not to mimic the solubility parameter?

This investigation reports the controlled transition from disordered/nano-segregated poly(styrene- b -pentafluorostyrene) (PS- b -PPFS)-based block copolymers after a subsequent para -fluoro/thiol click reaction with different functional thiol agents.