Activated persulfate by iron-carbon micro electrolysis used for refractory organics degradation in wastewater: a review

With the rapid economic development, the discharge of industrial wastewater and municipal wastewater containing many refractory organic pollutants is increasing, so there is an urgent need for processes that can treat refractory organics in wastewater. Iron-carbon micro electrolysis and advanced oxidation based on persulfate radicals (SO₄^-·) have received much attention in the field of organic wastewater treatment. Iron-carbon micro electrolysis activated persulfate (Fe-C/PS) treatment of wastewater is characterized by high oxidation efficiency and no secondary pollution. This paper reviews the mechanism and process of Fe-C/PS, degradation of organics in different wastewater, and the influencing factors. In addition, the degradation efficiency and optimal reaction conditions (oxidant concentration, catalyst concentration, iron-carbon material, and pH) of Fe-C/PS in the treatment of refractory organics in wastewater are summarized. Moreover, the important factors affecting the degradation of organics by Fe-C/PS are presented. Finally, we analyzed the challenges and the prospects for the future of Fe-C/PS in application, and concluded that the main future directions are to improve the degradation efficiency and cost by synthesizing stable and efficient catalysts, optimizing process parameters, and expanding the application scope.