等结构
化学
三聚体
碲
双折射
镓
结晶学
随机六聚体
热液循环
六方晶系
非线性光学
无机化学
晶体结构
化学工程
有机化学
光学
非线性系统
工程类
物理
二聚体
量子力学
作者
Peng‐Fei Li,Chun‐Li Hu,Fanzuo Kong,Jiang‐Gao Mao
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2023-05-24
卷期号:62 (22): 8494-8499
被引量:6
标识
DOI:10.1021/acs.inorgchem.3c01428
摘要
The exploration of novel inorganic tellurites is significant because of their promising applications in nonlinear-optical materials and birefringent materials. Herein, three new aluminum/gallium tellurites, namely, NaAl(Te4O10) (1), AgAl(Te4O10) (2), and K2Ga2(HTe6O16)(HTeO3) (3), have been successfully obtained by mild hydrothermal reactions. The isostructural compounds 1 and 2 contain the Te3O8 trimer, while compound 3 contains an unprecedented Te6O16 hexamer. Notably, all three compounds exhibit large birefringence values of over 0.1 at 532 nm, which are currently the largest reported birefringence values among tellurium(IV) oxides without additional anionic groups.
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