膦酸盐
光催化
肟
分子间力
氧化还原
化学
键裂
可见光谱
劈理(地质)
组合化学
光化学
材料科学
有机化学
催化作用
分子
复合材料
光电子学
断裂(地质)
作者
Yonghong Li,Wang Chunhai,Su-Qian Gao,Feng‐Ming Qi,Shang‐Dong Yang
摘要
A novel type of oxime phosphonate was synthesized and used in the intermolecular cascade radical addition reaction of alkenes to access β-aminophosphonates via visible-light-driven N-centered iminyl radical-mediated and redox-neutral selective C-P single-bond cleavage in an active phosphorus radical route. The procedure is characterized by its ability to achieve the construction of Csp3-P and Csp3-N bonds without the requirement for oxidants and bases.
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