The electrochemical performances of each component of the additive(composed of SP,polyether,quaternary ammonium salt,etc.)used in throughhole plating were investigated in detail by linear sweep voltammetry,A.C.impedance and open circuit potential-time,and the covering power of the combined additive was also investigated at different temperatures with inner-hole method.It was found that the covering power of the additive is good. The through-hole plating power of the combined additive was also investigated by RDE simulation.