过氧二硫酸盐
氢氧化物
光催化
催化作用
氧化物
电子顺磁共振
降级(电信)
化学
赤泥
种姓
氧气
材料科学
光化学
无机化学
电子结构
有机化学
物理化学
电信
物理
核磁共振
计算机科学
计算化学
作者
Qingyong Li,Guangtao Wei,Guangxiang Duan,Linye Zhang,Zhongmin Li,Zhi-Xian Wei,Zhou Qian,Ruinan Pei
标识
DOI:10.1016/j.seppur.2022.120733
摘要
In this work, a low-cost and oxygen vacancies (OVs) enriched mixed metal oxide (M−RM/MMO) derived from red mud-based layered double hydroxide (M−RM/LDH) was applied as an efficient peroxydisulfate (PDS) activator to realize the degradation of ciprofloxacin (CIP) under visible light (VL) irradiation. The optimal composite of M−RM/MMO-700 exhibited good performance, and approximately 87.4% of CIP (10 mg/L) could be degraded at 60 min via the photocatalysis activation of PDS (1.0 mM) over M−RM/MMO-700 (0.2 g/L). The result indicated the abundant OVs in M−RM/MMO-700 could improve light absorption and promote electron-hole separation, both of which were favorable for the activation of PDS, resulting in promoting the generation of active species in M−RM/MMO-700/PDS/VL system. Quenching experiments and EPR technology indicated that O2−, 1O2 and h+ were the main active species for the degradation of CIP. The M−RM/MMO catalyst possessed excellent reusability, stability and magnetic behavior in use. The degradation pathways of CIP were deduced based on DFT calculation and LC-MS analysis. Based on the quantitative structure–activity relationship (QSAR), the ecotoxicity of the degradation intermediates was analyzed in detail. This work provided a new insight for future designing of red mud-based LDHs-derived MMO heterogeneous catalyst with abundant OVs to efficiently treat antibiotics wastewater via the photocatalysis activation of PDS.
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