纤维素
材料科学
扫描电子显微镜
醋酸纤维素
复合材料
纳米纤维
氯化物
再生纤维素
极限抗拉强度
高分子科学
纤维素纤维
牛皮纸
纤维
化学工程
染色
脆性
图层(电子)
光学显微镜
作者
Jianan Liu,Yulong Peng,Huiming Fan,Yibin Lin,Wanqi Zhou
标识
DOI:10.1515/npprj-2025-0055
摘要
Abstract Paper relics tend to deteriorate and become brittle during long-term preservation. Cellulose as a major component of paper is commonly utilized for reinforcing paper materials. In this study, the solutions of cellulose were prepared using three different solvents: 1-butyl-3-methylimidazolium chloride ([Bmim]Cl),1-butyl-3-methylimidazolium acetate ([Bmim]Ac) and N-methylmorpholine-N-oxide hydrate (NMMO/H 2 O). A dyeing and labeling method is employed to demonstrate that these solutions could effectively penetrate into the interior of the paper and form regenerated cellulose. Scanning electron microscopy (SEM) analysis revealed the formation of a continuous cellulose layer on the surface of the treated paper samples. All samples were subjected to the same reinforcement procedure followed by accelerated aging tests. The mechanical properties, whiteness, and chromatic aberration of the samples were evaluated. Results indicated that the solution of cellulose dissolved in [Bmim]Ac achieved the most favorable balance between reinforcement efficacy and preservation of the original paper properties, when the amount of cellulose added was 6 g/m 2 , the tensile index increased by 26.16 %, with a chromatic aberration value of 1.86 observed before and after reinforcement. That study provides a new approach for the application of cellulose solutions in the conservation of paper-based cultural heritage.
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