Comparison of the antioxidant capacity of sesamol esters in gelled emulsion and non-gelled emulsion

The antioxidant capacity of sesamol esters in gelled emulsion was investigated in comparison with non-gelled emulsion to assess the role of mass transfer on their antioxidant capacity. Initiation phase and propagation phase kinetic parameters of peroxidation was calculated using a sigmoidal model. Sesamol esters showed higher antioxidant activity than sesamol in gelled emulsion and non-gelled emulsion. Sesamyl acetate, sesamyl butyrate, and sesamyl hexanoate had no synergistic effect with sesamol in gelled emulsion, while in non-gelled emulsion sesamyl butyrate exhibited a slight synergistic effect with sesamol. The antioxidant activity of sesamyl acetate and sesamyl hexanoate in non-gelled emulsion samples were higher than those of gelled emulsion samples, while sesamyl butyrate exhibited higher antioxidant activity in gelled emulsion than that of non-gelled emulsion. The cut-off effect hypothesis was observed in gelled emulsion, while this hypothesis was disappeared in non-gelled emulsion. During propagation phase, sesamol esters remained active and exhibited inhibitory effect.