化学
合成子
羧化
铜
催化作用
卤化物
双功能
三键
有机化学
组合化学
双键
作者
Yu‐Fei Song,Yu Zhang,Zhengkai Chen,Xiao‐Feng Wu
标识
DOI:10.1002/ajoc.202200237
摘要
Abstract As an ideal one‐carbon synthon, CO 2 has been successfully utilized in diverse carboxylation reactions to construct a series of value‐added products. Among various transition‐metal catalysts, the inexpensive copper complexes exhibit unique catalytic activity in carboxylation reactions. This review summarizes the recent developments in copper‐catalyzed carboxylation reactions with CO 2 , the contents of which are divided into five parts based on the type of the substrates or products: organic halides and their surrogates, C−C double bonds, C−C triple bonds, C−H bonds and the synthesis of heterocycles.
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