废止
化学
炔烃
喹啉
催化作用
钌
基质(水族馆)
氧化磷酸化
卡宾
共轭体系
组合化学
分子氧
药物化学
光化学
有机化学
生物化学
海洋学
聚合物
地质学
作者
Monuranjan Konwar,Nitumoni Hazarika,Animesh Das
标识
DOI:10.1021/acs.orglett.4c00542
摘要
The ruthenium/O2-catalyzed oxidative annulation reaction of imidazo[1,5-a]quinolin-2-ium salts with alkynes via N-heterocyclic carbene-directed C–H activation to obtain π-conjugated fused imidazo[1,5-a]quinolin-2-ium derivatives is reported. Molecular oxygen has been explored as an economic and clean oxidant and an alternative to metal oxidants. The current protocol exhibits a wide range of substrate scope including bioactive (±)-α-tocopherol derivatives. Moreover, most of the annulated products show strong fluorescence properties, indicating their potential for making new light-emitting materials.
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