荧光粉
兴奋剂
离子
发光
发射强度
材料科学
绿灯
分析化学(期刊)
热液循环
能量转移
离子键合
热稳定性
光电子学
化学
蓝光
化学工程
环境化学
分子物理学
有机化学
工程类
作者
Miao Yan,Lina Liu,Yabin Wang,Yifan Liu,Xiaolin Pei,Lili Yang,Hai Lin,Shasha Li,Wen Yang,Zhong‐Min Su,Chun Li,Fanming Zeng
标识
DOI:10.1016/j.jlumin.2024.120438
摘要
In this study, color-adjustable Sr2YF7: xDy3+, and yTb3+ light-emitting phosphors were synthesized through the hydrothermal method. Systematic experiments were performed to determine the optimal doping concentration for Sr2YF7: xDy3+ phosphor with x = 0.03, resulting in a distinctive light blue emission band attributed to the 4F9/2 → 6H15/2 transition. The energy transfer within the double-doped system of Sr2YF7: Dy3+, yTb3+ (y = 0, 0.06–0.1) was examined by analyzing spectral overlap and reductions in emission lifetimes. Moreover, the mechanism governing this energy transfer phenomenon was investigated. The concentration proportion of Dy3+/Tb3+ in Sr2YF7 phosphors was modulated to achieve color modulation, transitioning from light blue to vibrant green emissions in Sr2YF7: Dy3+, Tb3+ samples. The intensity of green emission increased with increasing Tb3+ ion concentrations because of the dynamics of energy migration from Dy3+ to Tb3+ levels (4F9/2 + 7F6 → 6H15/2 + 5D4). Based on calculations using steady-state rate equations, Tb3+ ion doping effectively reduced ionic spacing and consequently amplified the green emission. Furthermore, the results indicated that the luminous intensity ratio of Sr2YF7: 0.03Dy3+, 0.07 Tb3+ phosphors at 423/303K was notably high at 93.59 %, indicating high thermal stability. Thus, Sr2YF7 phosphors co-doped with Dy3+ and Tb3+ emerge as potential candidates for application in advanced illumination technologies.
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