Superflexible Artificial Soft Wood

Abstract Soft woods have attracted enormous interest due to their anisotropic cellular microstructure and unique flexibility. The conventional wood‐like materials are usually subject to the conflict between the superflexibility and robustness. Inspired by the synergistic compositions of soft suberin and rigid lignin of cork wood which has good flexibility and mechanical robustness, an artificial soft wood is reported by freeze‐casting the soft‐in‐rigid (rubber‐in‐resin) emulsions, where the carboxy nitrile rubber confers softness and rigid melamine resin provides stiffness. The subsequent thermal curing induces micro‐scale phase inversion and leads to a continuous soft phase strengthened by interspersed rigid ingredients. The unique configuration ensures crack resistance, structural robustness and superb flexibility, including wide‐angle bending, twisting, and stretching abilities in various directions, as well as excellent fatigue resistance and high strength, overwhelming the natural soft wood and most wood‐inspired materials. This superflexible artificial soft wood represents a promising substrate for bending‐insensitive stress sensors.