Iron‐Catalyzed Cross‐Coupling Reactions of Alkyl Grignard Reagents with Alkenyl Carbonate

Herein, we report the alkylation of alkenyl carbonates using alkyl Grignard reagents and iron catalysis to generate C(sp2)–C(sp3) bonds and provide synthetically useful yields over a range of substrates. The transformation allows the alkylation of a wide range of substrates, including aromatic rings, alkanes, cycloalkanes, heterocycles. This reaction has introduced a new family of electrophiles to the iron‐catalyzed cross‐coupling reactions.