色素敏化染料
电解质
光电流
开路电压
化学
能量转换效率
太阳能电池
肖特基势垒
短路
化学工程
光化学
电流密度
材料科学
光电子学
电压
电极
物理化学
工程类
物理
二极管
量子力学
作者
Vivekanand Gondane,Parag Bhargava
标识
DOI:10.1016/j.electacta.2016.05.079
摘要
Electrolyte is an important component of dye sensitised solar cells (DSSC). Its composition, in particular, additives controls the energetic at the TiO2/dye/electrolyte interface, influencing the performance of dye solar cell. We report here for the first time the use of 8-Hydroxyquinoline (8HQ) as an electrolyte additive to replace costly, volatile 4-tert-butyl pyridine (TBP). Due to its unique structural feature containing hydroxyl and amine group, 8HQ results in remarkable difference in the energy band alignment at the TiO2/dye/electrolyte interface with respect to that of TBP, as revealed by photocurrent density and Mott-Schottky analysis. Apart from this band shift, 8HQ is very effective in suppressing back electron transfer resulting in enhancement in open circuit voltage. Compared to TBP, additive 8HQ resulted in ∼22% increase in Jsc, with minor loss in Voc (∼5.8%) and 15% increase in photoconversion efficiency with N3 dye. Overall, we found that 8HQ is a highly effective additive in tailoring the TiO2/dye/electrolyte interface which results in superior performance of dye sensitized solar solar cells as compared to cells with TBP as the additive.
科研通智能强力驱动
Strongly Powered by AbleSci AI