Solid-State NMR in Materials Science: Principles and Applications

作者
Vladimir I. Bakhmutov
摘要

General Principles of Pulsed NMR and NMR Techniques Early History of NMR in the Solid State in the External Magnetic Field Effects of Radio Frequency Pulses From Macroscopic Magnetization to Nuclear Relaxation and Shapes of NMR Signals Parameters Characterizing in the External Magnetic Field Introducing NMR Equipment and NMR Experiments Main Principles of Two-Dimensional NMR Enhancement of Sensitivity in NMR On Amorphous Materials as Potential Objects in Solid-State NMR Studies: Common and Key Problems Hybrid Materials Polymer Solids Systems Based on Nanostructures Wood and Wood Components Glasses Zeolites Design of Porous and Layered Molecular Systems Features of Solid-State NMR: Diamagnetic Materials From Isotropic Chemical Shifts to Magnetic Shielding Tensors with a Spin of 1/2 Quadrupolar in Solids Detection of NMR Signals in Solids: Common Aspects High-Power Decoupling Multi-Quantum NMR Experiments Dipolar Recoupling NMR Techniques Sideband Manipulations Zero-Field Solid-State NMR Experiments Solid-State NMR Imaging Practice of Multinuclear NMR in Diamagnetic Solids: General Information and Examples of Applications Structural Information by Increasing the Spectral Resolution in Multinuclear Solid-State NMR Probing Proximities of and Measurements of Internuclear Distances in Diamagnetic Solids 31P Solid-State NMR Solid-State NMR of Halogen and Oxygen Solid-State NMR of Oxide Materials: 51V, 93Nb, and 181Ta Solid-State 13C NMR: Wood and Wood Products 2H NMR in Solids at Deuterium Natural Abundance Between Solution- and Solid-State NMR: Nanoparticles and Suspensions Dynamics in Diamagnetic Materials from Solid-State NMR: Methods, Measurements, and Analysis Variable-Temperature Solid-State NMR Experiments and a Line-Shape Analysis Molecular Mobility from the Solid-State NMR Relaxation One- and Two-Dimensional Exchange Solid-State NMR Spectroscopy Molecular Mobility from the Cross-Polarization NMR Experiments Molecular Mobility from Magnetic Relaxation Dispersion Experiments Strategies in Solid-State Multinuclear NMR: Studies of Diamagnetic Porous Materials Porosity of Materials from NMR Structural Features of Silica Lattice and Surface by Solid-State 1H 29Si, 27Al, and 17O NMR Spectra Molecular Mobility in Diamagnetic Porous Materials Paramagnetic Effects in Solid-State NMR Theoretical Aspects Nuclear Relaxation in the Presence of Unpaired Electrons Practical Consequences from the Theory of Paramagnetic Effects 1H, 31P, 13C, 2H, 29Si, 7Li, and 6Li NMR Spectra of Paramagnetic Solids 51V and 55Mn NMR Spectra of Paramagnetic Solids Special NMR Techniques for Observations of Target Relaxation Measurements and Relaxation Times in Paramagnetic Solids Strategy in NMR Studies of Amorphous Porous Paramagnetic Materials Intense Sideband Patterns in MAS NMR Spectra of Paramagnetic Amorphous Materials and Their Analysis Direct Detection of the Closest to Paramagnetic Ions in Porous Materials by the Hahn-Echo Mapping NMR Experiments NMR Relaxation Approaches to Structure of Porous Amorphous Paramagnetic Silica-Based Materials: From Experiments to Models and Interpretations Protocol for Quantification of Invisible Nuclei in MAS NMR Concluding Remarks

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