波函数
激发态
物理
原子物理学
能量(信号处理)
组态交互作用
极化(电化学)
量子力学
化学
物理化学
作者
Lei Wu,Jun Jiang,Zhongwen Wu,Yongjun Cheng,Gediminas Gaigalas,Chenzhong Dong
出处
期刊:Physical review
[American Physical Society]
日期:2022-07-15
卷期号:106 (1)
被引量:4
标识
DOI:10.1103/physreva.106.012810
摘要
An accurate determination of various parameters of ${\mathrm{Ar}}^{13+}$ is presented in this work. The wave functions and energy levels of the low-lying states within the configurations of $2{s}^{2}2p$ and $2s2{p}^{2}$ are calculated using the fully relativistic multiconfiguration Dirac-Hartree-Fock method, while the wave functions of higher excited states with the configurations $2{s}^{2}nl\phantom{\rule{4pt}{0ex}}(n\ensuremath{\ge}3$, $l=s,p,d)$ are obtained using the relativistic configuration interaction plus core polarization method. Then, the absorption oscillator strengths, transition probabilities, polarizabilities, and $g$ factors are determined. The contributions of electron correlation effects, Breit interaction, and quantum electrodynamics effects are also investigated. The present results agree well with the available theoretical and experimental results. The $g$ factors of the $2{s}^{2}2p\phantom{\rule{4pt}{0ex}}^{2}P_{1/2,3/2}$ states agree with the experimental measurements on a level of ${10}^{\ensuremath{-}6}$.
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