We analytically establish the role of a spectrum of Lyapunov exponents in the evolution of phase-space distributions $\ensuremath{\rho}(p,q).$ Of particular interest is ${\ensuremath{\lambda}}_{2},$ an exponent that quantifies the rate at which chaotically evolving distributions acquire structure at increasingly smaller scales and is generally larger than the maximal Lyapunov exponent \ensuremath{\lambda} for trajectories. The approach is trajectory independent and is therefore applicable to both classical and quantum mechanics. In the latter case we show that the $\ensuremath{\Elzxh}\ensuremath{\rightarrow}0$ limit yields the classical, fully chaotic, result for the quantum cat map.