氢解
化学
硝基苯
苯胺
无机化学
电化学
水溶液
雷尼镍业
镍
铜
循环伏安法
塔菲尔方程
电极
催化作用
有机化学
物理化学
作者
André Cyr,Pierre Huot,G. Belot,Jean Lessard
标识
DOI:10.1016/0013-4686(90)85052-o
摘要
The preparative electrochemical reduction of nitrobenzene, phenylhydroxylamine, azoxybenzene, azobenzene, and hydrazobenzene was studied under controlled potential conditions at Devarda copper and Raney nickel electrodes in neutral (E = −0.6 V vs sce) and basic (E = −1.0 V vs sce) aqueous methanolic solutions. The reduction of NB at Devarda copper electrodes was carried out also at constant current (∼ 2.2 A dm−2) in basic aqueous methanol. The lifetime of the Devarda copper electrode was about 21 days under these conditions. In all cases, aniline was obtained in high chemical (85–100%) and current (80–100%) yields, thus showing that hydrogenolysis of the NO bond of phenylhydroxylamine and of the NN bond of hydrazobenzene is an efficient electrochemical process at these electrodes. An electrocatalytic hydrogenation (ECH) mechanism is most probably operating in this hydrogenolysis process. For the reduction of nitrobenzene to phenylhydroxylamine and of azoxybenzene to hydrazobenzene, an ECH mechanism and/or an electronation—protonation (EP) mechanism can be involved.
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