电化学
扫描电子显微镜
阴极
材料科学
透射电子显微镜
电极
微观结构
氧化还原
过渡金属
化学工程
分析化学(期刊)
化学
纳米技术
冶金
复合材料
催化作用
色谱法
物理化学
生物化学
工程类
作者
Yang Liu,Shaohua Luo,Yafeng Wang,Zhan Yang,Qing Wang,Yahui Zhang,Xin Liu,Wenning Mu,Fei Teng
标识
DOI:10.1016/j.cej.2020.126578
摘要
A series of Cu-doped layered P2-type Na0.67Ni0.33-xCuxMn0.67O2 (x = 0, 0.05, 0.10, 0.15, 0.20, 0.33) were fabricated using a convenient solid-state method and studied as cathode materials for sodium-ion batteries. The microstructure and morphology of the cathode materials were examined by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM) techniques. The electrochemical characteristics of Na0.67Ni0.33-xCuxMn0.67O2 samples have been investigated systematically and it shows good capacity retention, cycling stability and rate performance by introducing electrochemically active Cu2+ ions as substituents. When x= 0.15, the sample delivers an initial discharge capacity of 120 mAh g−1 at 0.1 C in the voltage range 2–4.3 V with a capacity retention of 78% after 200 cycles, and a reversible capacity of 62 mAh g-1 can be obtained at a high current rate of 20 C. Compared with the pristine compound, the enhanced electrochemical performance can be attributed to the Cu2+ inserted into the transition metal (TM) layer, which stabilizes the P2-phase structure against P2-O2 phase transition when charging to high voltage. Meanwhile, the presence of copper also contributes to the reversible capacity based on the Cu2+/Cu3+ redox reaction. This strategy can improve the cyclability and rate performance by enhancing the stability between TM layers.
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