乙烯醇
化学
硝酸银
硼酸
银纳米粒子
聚合
纳米复合材料
核化学
高分子化学
傅里叶变换红外光谱
还原剂
纳米颗粒
聚合物
有机化学
材料科学
化学工程
纳米技术
工程类
作者
Titilope John Jayeoye,Oladipupo Odunayo Olatunde,Soottawat Benjakul,Thitima Rujiralai
标识
DOI:10.1016/j.colsurfb.2020.111112
摘要
In this work, the synthesis method and applications of nanocomposite polymer stabilized silver nanoparticles (AgNPs) are reported. 3-Aminophenyl boronic acid (3APBA) was used as a reductant of silver nitrate which acted as an oxidant for the polymerization of 3APBA through in situ chemical oxidative polymerization to poly(3-aminophenyl boronic acid) or PABA. The formation of PABA in the reaction mixture led to particle agglomeration owing to PABA poor solubility. However, in the presence of hydrophilic poly(vinyl alcohol) (PVA), PABA binds to the free hydroxyl group of PVA to form a composite polymer (PABA-PVA), which perfectly stabilized the formed AgNPs. Succinctly, PVA acted as a solubilizer and stabilizer for (PABA-PVA)AgNPs synthesis. Synthesis was optimized and sharp absorption peaks at 290 nm and 426 nm were observed, attributing to the π-π* transition of the benzenoid ring of PABA and the characteristic absorption spectrum of AgNPs, respectively. (PABA-PVA)AgNPs was characterized using UV-vis, TEM, FESEM, EDX, XRD, FTIR, TGA/DTG, DLS and zeta potential analysis. In addition, the antibacterial, antioxidant and metal chelating capacities of (PABA-PVA)AgNPs were evaluated. The (PABA-PVA)AgNPs exhibited significant antibacterial activity against Escherichia coli and Listeria monocytogenes, and good antioxidant and metal chelating properties of (PABA-PVA)AgNPs, thus validating its attractive biological applications.
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