Anchoring of Formamidinium Lead Bromide Quantum Dots on Ti3C2 Nanosheets for Efficient Photocatalytic Reduction of CO2

Metal halide perovskite with a suitable energy band structure and excellent visible-light response is a prospective photocatalyst for CO₂ reduction. However, the reported inorganic halide perovskites have undesirable catalytic performances due to phase-sensitive and severe charge carrier recombination. Herein, we anchor the FAPbBr₃ quantum dots (QDs) on Ti₃C₂ nanosheets to form a FAPbBr₃/Ti₃C₂ composite within a Schottky heterojunction for photocatalytic CO₂ reduction. Upon visible-light illumination, the FAPbBr₃/Ti₃C₂ composite photocatalyst exhibits an appealing photocatalytic performance in the presence of deionized water. The Ti₃C₂ nanosheet acts as an electron acceptor to promote the rapid separation of excitons and supply specific catalytic sites. An optimal electron consumption rate of 717.18 μmol/g·h is obtained by the FAPbBr₃/0.2-Ti₃C₂ composite, which has a 2.08-fold improvement over the pristine FAPbBr₃ QDs (343.90 μmol/g·h). Meanwhile, the FAPbBr₃/Ti₃C₂ photocatalyst also displays a superior stability during photocatalytic reaction. This work expands a new insight and platform for designing superb perovskite/MXene-based photocatalysts for CO₂ reduction.