电化学
对映体
手性(物理)
分子识别
对映选择合成
组合化学
氨基酸
化学
金属
循环伏安法
金属有机骨架
分子
材料科学
纳米技术
计算化学
有机化学
催化作用
物理化学
手征异常
电极
物理
生物化学
费米子
量子力学
吸附
Nambu–Jona Lasinio模型
作者
Xiaohui Niu,Simeng Yan,Jinliang Chen,Hongxia Li,Kunjie Wang
标识
DOI:10.1016/j.electacta.2021.139809
摘要
Chiral metal-organic frameworks (MOF) have received extensive attention from researchers due to their chiral properties and potential applications in chiral-related fields. However, the construction of chiral metal-organic framework remains challenging due to the unpredictability of the synthesis process and the difficulty in keeping chirality during the growth of chiral MOF. Herein, a chiral MOF (D-His-ZIF-8) is reported for the construction of electrochemical sensing interface, which was synthesized via in-situ substitution of 2-methylimidazole on ZIF-8 by D-histidine (D-His). The introduction of Ketjen Black (KB) to the D-His-ZIF-8 sensing interface can improve its conductivity. The electrochemical recognition results show that KB/D-His-ZIF-8 has enantiodiscrimination ability for amino acids in voltammetry experiments. The best recognition efficiency is observed with Trp enantiomers. The recognition mechanism shows that the chiral nanochannel of D-His-ZIF-8 is conducive to the binding of L-amino acid, which will lead to the recognition of chiral molecules of different configurations. This research points to the possibility of developing further chiral recognition protocols based on D-His-ZIF-8, particularly with the suggested improvement in the preparation procedure of chiral MOF.
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