Gold Nanoparticle Functionalized Artificial Nacre: Facile in Situ Growth of Nanoparticles on Montmorillonite Nanosheets, Self-Assembly, and Their Multiple Properties

Artificial nacre based on clay nanosheets have been emerging as a new generation of bioinspired materials due to their super mechanical, fire-retardant, heat-shield, and gas barrier properties. Functional design in artificial nacre is highly demanded to further broaden the applications of these promising bioinspired materials. However, there is rarely a report on the functionalization of artificial nacre at present possibly due to the lack of a feasible strategy to introduce functional components in nacre-like materials without weakening other properties. In this study, we report a feasible method to fabricate artificial nacre-like functional hybrid films by using Au nanoparticle (NP) modified natural clay montmorillonite (MTM) nanosheets as efficient two-dimensional building blocks. First, Au NPs-chitosan-MTM hybrid nanosheets were prepared and homogeneously dispersed in deionized water by the facile in situ growth of Au NPs on chitosan-MTM nanosheets. Then, the obtained Au NPs-chitosan-MTM hybrid nanosh...