电催化剂
多硫化物
材料科学
催化作用
电解质
锂硫电池
化学工程
电化学
锂(药物)
X射线光电子能谱
硫黄
阴极
纳米技术
电极
化学
冶金
物理化学
有机化学
医学
工程类
内分泌学
作者
Jian He,Amruth Bhargav,Arumugam Manthiram
出处
期刊:ACS Nano
[American Chemical Society]
日期:2021-04-23
卷期号:15 (5): 8583-8591
被引量:78
标识
DOI:10.1021/acsnano.1c00446
摘要
Lithium–sulfur (Li–S) batteries possess high theoretical specific energy but suffer from lithium polysulfide (LiPS) shuttling and sluggish reaction kinetics. Catalysts in Li–S batteries are deemed as a cornerstone for improving the sluggish kinetics and simultaneously mitigating the LiPS shuttling. Herein, a cost-effective hexagonal close-packed (hcp)-phase Fe–Ni alloy is shown to serve as an efficient electrocatalyst to promote the LiPS conversion reaction in Li–S batteries. Importantly, the electrocatalysis mechanisms of Fe–Ni toward LiPS conversion is thoroughly revealed by coupling electrochemical results and post mortem transmission electron microscopy, X-ray photoelectron spectroscopy, and in situ X-ray diffraction characterization. Benefiting from the good catalytic property, the Fe–Ni alloy enables a long lifespan (over 800 cycles) and high areal capacity (6.1 mA h cm–2) Li–S batteries under lean electrolyte conditions with a high sulfur loading of 6.4 mg cm–2. Impressively, pouch cells fabricated with the Fe–Ni/S cathodes achieve stable cycling performance under practically necessary conditions with a low electrolyte/sulfur (E/S) ratio of 4.5 μL mg–1. This work is expected to design highly efficient, cost-effective electrocatalysts for high-performance Li–S batteries.
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