静电纺丝
材料科学
化学工程
阳极
钠离子电池
热解
膜
储能
纳米纤维
电化学
碳纤维
法拉第效率
多孔性
复合数
纤维
电极
聚丙烯腈
电池(电)
纳米技术
复合材料
化学
聚合物
物理
工程类
量子力学
物理化学
功率(物理)
生物化学
作者
Kaiwen Xue,Yechen Si,Shuya Xie,Jingxuan Yang,Yan Mo,Baojun Long,Wei Wang,Peiyu Cao,Huixian Wei,Hongtao Guan,Elizabeth Michaelis,Guangyu Guo,Ye Yue,Changsheng Shan
标识
DOI:10.3389/fchem.2021.647545
摘要
It is important to develop new energy storage and conversion technology to mitigate the energy crisis for the sustainable development of human society. In this study, free-standing porous nitrogen-doped carbon fiber (PN-CF) membranes were obtained from the pyrolysis of Zn–MOF-74/polyacrylonitrile (PAN) composite fibers, which were fabricated in situ by an electrospinning technology. The resulting free-standing fibers can be cut into membrane disks and directly used as an anode electrode without the addition of any binder or additive. The PN-CFs showed great reversible capacities of 210 mAh g −1 at a current density of 0.05 A g −1 and excellent cyclic stability of 170.5 mAh g −1 at a current density of 0.2 A g −1 after 600 cycles in sodium ion batteries (SIBs). The improved electrochemical performance of PN-CFs can be attributed to the rich porous structure derived by the incorporation of Zn–MOF-74 and nitrogen doping to promote sodium ion transportation.
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