热重分析
差示扫描量热法
材料科学
电解质
聚合物
聚合
活化能
热分解
锂(药物)
高分子化学
化学
物理化学
有机化学
电极
复合材料
内分泌学
物理
热力学
医学
作者
Libo Li,Ming‐Hua Xie,Yonghong Zhang,Yanping Xu,Jia Li,Yuhang Shan,Yangmingyue Zhao,Da Zhou,Xiaochuan Chen,Wenjun Cui
标识
DOI:10.1007/s10008-021-04965-3
摘要
This work obtained gel polymer electrolytes (GPEs) via in situ polymerization of methyl methacrylate (MMA) in the environment of lithium bis(trifluoromethane sulfonyl)imide (LiTFSI) and N-methyl-N-propylpyrrolidinium bis(trifluoromethane sulfonyl)amide (Py13TFSI). The thermogravimetric analysis (TGA) and the differential scanning calorimeter (DSC) determined the non-isothermal decomposition of Py13TFSI/LiTFSI/PMMA polymer electrolyte for Li-ion battery. TGA, DSC, and the infrared graph analyzed thermodynamic properties, and the results showed the addition of Py13TFSI significantly improved the thermostability of electrolytes. Flynn-Wall-Ozawa (Ozawa), Kissinger-Akahira-Sunose (KAS), and Friedman methods applied for kinetics characteristics to activation energy (Ea) and pre-exponential factor (A). The Ea value from Ozawa and KAS methods was 208.478 kJ mol−1 and 207.423 kJ mol−1, respectively.
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