Knoevenagel冷凝
结晶度
介孔材料
催化作用
热稳定性
材料科学
吸附
化学工程
化学
金属有机骨架
有机化学
复合材料
工程类
作者
Kaushik Naskar,Suvendu Maity,Himadri Sekhar Maity,Chittaranjan Sinha
出处
期刊:Molecules
[Multidisciplinary Digital Publishing Institute]
日期:2021-08-31
卷期号:26 (17): 5296-5296
被引量:22
标识
DOI:10.3390/molecules26175296
摘要
[Cu(CPA)(BDC)]n (CPA = 4-(Chloro-phenyl)-pyridin-4-ylmethylene-amine; BDC = 1,4-benzenedicarboxylate) has been synthesized and structurally characterized by single crystal X-Ray diffraction measurement. The structural studies establish the copper (II) containing 2D sheet with (4,4) square grid structure. The square grid lengths are 10.775 and 10.769 Å. Thermal stability is assessed by TGA, and subsequent PXRD data establish the crystallinity. The surface morphology is evaluated by FE-SEM. The N2 adsorption−desorption analysis demonstrates the mesoporous feature (∼6.95 nm) of the Cu-MOF. This porous grid serves as heterogeneous green catalyst with superficial recyclability and thermal stability and facilitates organic transformations efficiently such as, Click and Knoevenagel reactions in the aqueous methanolic medium.
科研通智能强力驱动
Strongly Powered by AbleSci AI