果胶
吸附
表面改性
胺气处理
二氧化碳
涂层
傅里叶变换红外光谱
化学工程
化学
材料科学
有机化学
生物化学
工程类
作者
John Andrew Kane Jovellana,Bryan B. Pajarito
出处
期刊:Key Engineering Materials
日期:2019-05-03
卷期号:801: 179-184
被引量:2
标识
DOI:10.4028/www.scientific.net/kem.801.179
摘要
Increasing carbon dioxide (CO 2 ) levels in the atmosphere caused by excessive greenhouse gas emissions is strongly associated to global warming and climate change. This study aims to prove the feasibility of using pectin as the backbone for amine functionalization with application as coating on zeolites for carbon dioxide capture. Characterization of the solutions using FTIR and of the adsorbents using SEM demonstrated the successful modification of pectin using NH 3 and TETA as alternative amine-functionalized coating for adsorbent. It has been reported for the first time that the polysaccharide pectin can be aminated and modified for CO 2 capture upon coated on substrates such as zeolites. The adsorption capacities at 5% breakthrough of the adsorbents coated with the modified pectin are 2.24 mmol/CO 2 g adsorbent and 2.28 mmol/CO 2 g adsorbent, when coated with NH 3 -modified and TETA-modified pectin, respectively. It is recommended for further study to synthesize substrates with higher surface area, and optimize the formulations of the pectin modification.
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