聚吡咯
材料科学
傅里叶变换红外光谱
X射线光电子能谱
聚酯纤维
表面改性
接触角
扫描电子显微镜
图层(电子)
化学工程
硫酸
磺酸
复合材料
沉积(地质)
聚合物
高分子化学
聚合
工程类
古生物学
生物
冶金
沉积物
作者
Zhenyun Zhao,Jing Zhou,Tao Fan,Lanqian Li,Zulan Liu,Yiping Liu,Ming Lü
标识
DOI:10.1016/j.matchemphys.2017.09.062
摘要
Abstract A simple and effective surface modification of polyester (PET) fabrics with H2SO4 (sulfuric acid) to improve the interfacial deposition of polypyrrole (PPy) on PET fabrics was presented in our work. Effects of H2SO4 concentration on hydrophilicity of PET fabrics were analyzed by water contact angle measurements. Effects of H2SO4 modification on deposition of PPy were investigated by electrical resistivity and color depth of fabrics measurements. Besides, the adhesion of PPy on PET fabrics was also discussed. The PPy-deposited PET fabrics were determined by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). FTIR and XPS results showed that sulfonic acid groups appeared on PET fibers after modification which were contributed to improving deposition of PPy on PET fabrics. The improved deposition increased electrical conductivity of fabrics.
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