Homoallyl alcohol as an allylation reagent for termination of the Catellani–Lautens reaction via retro-allylation

A palladium/norbornene-catalyzed ortho -amination/allylation of aryl iodides was developed for the construction of ortho -aminated allylbenzene by using N -benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent.