Recent Research Progress of Organic Small‐Molecule Semiconductors with High Electron Mobilities

Abstract Organic electronics has made great progress in the past decades, which is inseparable from the innovative development of organic electronic devices and the diversity of organic semiconductor materials. It is worth mentioning that both of these great advances are inextricably linked to the development of organic high‐performance semiconductor materials, especially the representative n ‐type organic small‐molecule semiconductor materials with high electron mobilities. The n ‐type organic small molecules have the advantages of simple synthesis process, strong intermolecular stacking, tunable molecular structure, and easy to functionalize structures. Furthermore, the n ‐type semiconductor is a remarkable and important component for constructing complementary logic circuits and p ‐ n heterojunction structures. Therefore, n ‐type organic semiconductors play an extremely important role in the field of organic electronic materials and are the basis for the industrialization of organic electronic functional devices. This review focuses on the modification strategies of organic small molecules with high electron mobility at molecular level, and discusses in detail the applications of n ‐type small‐molecule semiconductor materials with high mobility in organic field‐effect transistors, organic light‐emitting transistors, organic photodetectors, and gas sensors.