催化作用
磁铁矿
傅里叶变换红外光谱
铜
材料科学
扫描电子显微镜
透射电子显微镜
复合数
化学工程
降水
纳米颗粒
还原剂
光谱学
能量色散X射线光谱学
红外光谱学
多相催化
纳米技术
核化学
化学
冶金
复合材料
有机化学
量子力学
气象学
工程类
物理
作者
Mehran Badbedast,Amir Abdolmaleki,Dariush Khalili
标识
DOI:10.1002/slct.202203199
摘要
Abstract Synthesis of pyranopyrazoles using heterogeneous catalysts is among the most executed synthetic approaches in organic chemistry and has attracted much attention because of the atom economy and environmentally benign issues. Magnetite dopamine‐supported copper nanoparticles were created using a simple co‐precipitation technique and characterized by Fourier‐transform infrared spectroscopy (FTIR), x‐ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and vibrating sample magnetometry (VSM). The catalytic activity of the Fe 3 O 4 @PDA/CuCl 2 system was probed in the synthesis of structurally diverse pyranopyrazoles. It′s worth mentioning that the catalyst could be used at low loadings to produce pyranopyrazoles with high to acceptable in the absence of an external reducing agent. Additionally, the produced heterogeneous catalyst can be reused (by extracting with an external magnet) in six subsequent cycles without suffering a significant loss in catalytic activity. The high efficiency of the derivatives from about 70 % to 98 %, as well as the fact that the TON)1000–2500( and TOF)1000–5000 h −1 ) have attained the optimal amount, indicate the catalyst‘s high efficiency.
科研通智能强力驱动
Strongly Powered by AbleSci AI