Morphotropic phase boundary in pure perovskite lead titanate at room temperature

For many decades, great efforts have been devoted to pursue a large piezoelectric response by an intelligent design of morphotropic phase boundaries (MPB) in solid solutions, where tetragonal (T) and rhombohedral (R) structures coexist. For example, classical PbZr x Ti 1-x O 3 (PZT) and Pb(Mg 1/3 Nb 2/3 )O 3 -PbTiO 3 (PMN-PT) single crystals demonstrate a giant piezoelectric response near MPB. However, as the end member of these solids, perovskite structured PbTiO 3 , always adopts the T phase at room temperature. Here, we report a pathway to create room temperature MPB in a single-phase PbTiO 3 . The uniaxial stress along the c -axis drives a T-R phase transition bridged by a monoclinic (M) phase, which facilitates a polarization rotation in the mono-domain PbTiO 3 . Meanwhile, we demonstrate that the coexistence of T and R phases at room temperature can be achieved via an extremely mismatched heterointerface system. The uniaxial pressure is proved as an efficient way to break the inherent symmetry and able to substantially tailor the phase transition temperature T c. These findings provide new insights into MPB, offering the opportunity to explore the giant piezoelectric response in single-phase materials.